HEAT CAPACITIES OF AN IDEAL GAS

When heat capacity is constant over some temperature range δT,
Process Dependent Heat Capacities
- These two heat capacities are approximately the same for solids and liquids because of their low coefficient of volume expansion. Thus we usually do not make a distinction between the two for solids and liquids.
- In general the constant pressure heat capacity is larger that constant volume heat capacity for a gas because some of the heat that is added during a constant pressure process must go into work of expansion at a constant pressure rather than just all going into the internal thermal energy.
- The symbol δ is similar to a differential d except that Q is already change so that δQ is infinitesimal amount of heat flow. This is needed because in general the heat capacities are not constant but temperature dependent - meaning that it may take more energy to raisme one gram of a gas one degree C at a higher temperature be it a constant volume process or a constant pressure process.
Constant Volume Heat Capacity:
First Law
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δQ = δQ - 0
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| δW = 0 |
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δQ = ΔU |
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Applied to the definition of
constant volume heat capacity
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Integrating to find the Heat Flow
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- Since the volume can not expand (by definition) all the heat goes into the internal energy of the gas in a constant pressure process.
- This also means that the change in internal energy for any process can be calculated using the constant volume heat capacity regardless of the process.

- It is always possible to find the change in internal energy using the constant volume heat capacity regardless of type of process, i.e even if the process was a constant pressure or adiabatic process.
Constant Pressure Heat Capacity
First Law applied to constant pressure process
Definition of Enthalpy
- Chemist often use enthalpy because it lets them determine the heat flow in a constant pressure processes. Mixing and heating chemicals open to the air is a constant pressure process.
- The heat flow in or out during any process can be calculated using the constant pressure heat capacity regardless of the type of process process.
