HEAT CAPACITY (The Storage of Thermal Energy)
HEAT CAPACITY of a SYSTEM : (Most General Definition and the one we hardly ever use)
- CT = Total Amount of Heat Energy required to raise the temperature of some System 1oC.
- SI: J/ oC
For such a a system: Q = CT ΔT
- We hardly ever use this definition because every system would have a different CT even if it were made of the same substance. For example, a 100g of pure water and 50g of pure water would each have a different total heat capacity. The heat capacity CT is useful for composite systems composed of different substances like a mixture of a fixed amount of water and copper.
SPECIFIC HEAT CAPACITY of a SUBSTANCE : (Conventionally used in Physics)
- C = Amount of Heat Energy per kilogram that is required to raise the temperature of one kilogram of the substance 1oC.
- SI: J/(kg⋅oC) or J/kg/oC
For such a system: Q = m C ΔT
MOLAR HEAT CAPACITY of a SUBSTANCE : (Routinely used in Chemistry)
- c = Amount of Heat Energy per mole that is required to raise the temperature of 6.022x1023 molecules of the substance 1oC.
- SI: J/(mole⋅oC) or J/mole/oC
For such a system: Q = n c ΔT
VOLUMETRIC HEAT CAPACITY of a SUBSTANCE : (Commonly used in storage of Solar Energy)
- cv = Amount of Heat Energy per unit volume that is required to raise the temperature of one cubic meter of the substance 1oC.
- SI: J/(m3⋅oC)
For such a system: Q = V cv ΔT
- Historically, heat capacities have been expressed in oC rather than K (Kelvin) because most temperature devices measure temperatures in degrees Celsius. Technically, the units of heat capacity should be expressed in degrees K rather than degrees oC. However, ΔT has the same value regardless if T is measured in K or oC since the units of K and oC have the same size. Thus both system of units will give the same answer.