Kinetic Theory of Gases


Equipartition-of-Energy Theorem for an Ideal Gas

Monatomic Molecule
Rigid Diatomic Molecule
Vibrating Diatomic Molecule

Mean Free Path:


Molecular Velocities:

vav = Normal average or mean speed. Half the molecules have speed greater than vav and half are slower.
vrms = The square root of the average of the square of the velocity of the molecules in the gas.
vp = The speed at which the largest number of molecules move.


MAXWELL - BOLTZMANN VELOCITY DISTRIBUTION

Average Kinetic Energy of a Gas Molecule:

Most Probable Kinetic Energy of a Gas Molecule:

m = mass of gas molecule SI: kg
k = 1.380x10-23 J/K Boltzmann's Constant
T = Temperature of the Gas SI: K